Volume 609
Main Index

Issues 1-2, Pages 1-208 (8 September 2000)

Foreword Page 1

Binding modes of a mixed donor multidentate iminobisphosphane ligand to the triosmium cluster: the crystal structures of [{Os3(CO)11}2(PNCHP)], [Os3(μ-H)(μ3-PNCP)(CO)7] and [Os3(μ-H)(μ2-PNCP)(CO)8] Pages 2-9 Eric W. Ainscough*, Andrew M. Brodie*, Anthony K. Burrell, Steven M. F. Kennedy

Reactivity of [Re(η2-H2)(CO)2P3]+ cations with alkynes: preparation of vinylidene and propadienylidene complexes Pages 10-20 Gabriele Albertin, Stefano Antoniutti, Emilio Bordignon, Davide Bresolin

Early lanthanide organometallic hydrides: electronic and steric control of the stability Pages 21-28 Denise Barbier-Baudry, Alain Dormond, Marc Visseaux

The kinetics and mechanisms of reactions involving the dihydrogen complex trans-[FeH(H2)(DPPE)2]+ and related compounds Pages 29-35 Manuel G. Basallote, Joaquín Durán, M. Jesús Fernández-Trujillo, M. Angeles Máñez

An intramolecular N---HCo hydrogen bond and a structure correlation study of the pathway for protonation of the Co(CO)3L− anion (L=CO, PR3) Pages 36-43 Lee Brammer, Juan C. Mareque Rivas, Christopher D. Spilling

The ligand [Cp2MoH2] in complexes with Ag---S bonds Pages 44-52 Henri Brunner, Andrea Hollman, Manfred Zabel, Bernhard Nuber

An ‘atoms in molecules’ (AIM) analysis of the dihydrogen bond in organometallic compounds Pages 53-59 Maria José Calhorda, Pedro E. M. Lopes

Activation of E---H (E=Sn, Si, S) bonds by cyclooctadieneiridium pyridine-2-carboxylate and related compounds Pages 60-65 Laurence Carlton, Joseph J. Molapisi

Photodissociation and electronic spectroscopy of transition metal hydrides carbonyls: quantum chemistry and wave packet dynamics Pages 66-76 Marie Catherine Heitz, Dominique Guillaumont, Isabelle Cote-Bruand, Chantal Daniel

Synthesis and structure of [(η5-C5Me5)WCl2(μ-H)]2. A dinuclear tungsten hydride with a double bond formed from the reaction of BH3THF with (η5-C5Me5)WCl4 Pages 77-82 Melanie A. Peldo, Maoyu Shang, Thomas P. Fehlner

Bridging-terminal exchange in ansa-bridged tetrahydroborate niobocene compounds: a density functional study Pages 83-88 Nicholas J. Ashworth, Stephen L. J. Conway, Jennifer C. Green, Malcolm L. H. Green

The clusters HRu3W(η5-Cp)(CO)11−x(PPh3)xBH (x=1, 2): preparations, characterizations and the crystal structure of HRu3W(η5-Cp)(CO)10(PPh3)BH Pages 89-94 Catherine E. Housecroft, Dorn M. Nixon, Arnold L. Rheingold

H2 binding to and silane alcoholysis on an electrophilic Mn(I) fragment with tied-back phosphite ligands. X-ray structure of a Mn–CH2Cl2 complex Pages 95-103 Xinggao Fang, Jean Huhmann-Vincent, Brian L. Scott, Gregory J. Kubas

The heteronuclear cluster RuOs3(μ-H)2(CO)13 — a high yield synthesis, isomerism and a triphenylphosphine derivative Pages 104-109 Leonard Pereira, Weng Kee Leong, Siew Ying Wong

The effect of ancillary ligands on intramolecular proton---hydride (NHHIr) bonding in complexes of iridium(III) Pages 110-122 Sung Han Park, Alan J. Lough, Glenn P. A. Yap, Robert H. Morris

Studies on the reactivity of Nb(η5-C5H4SiMe3)2(X)(L), X=H,Cl; L=CNXylyl, CNCy, CO and Nb(η5-C5H4SiMe3)2(H)3 complexes toward the Lewis acids B(C6F5)3 and BF3 Pages 123-129 Antonio Antiñolo, Fernando Carrillo-Hermosilla, Juan Fernández-Baeza, Santiago García-Yuste, Antonio Otero, Javier Sánchez-Prada, Elena Villaseñor

Hydrosilylation of 1,4-bis(trimethylsilyl)-1-buten-3-ynes using late transition metal hydrides as catalyst precursors Pages 130-136 Yooichiroh Maruyama, Keigo Yoshiuchi, Fumiyuki Ozawa

Methods of enhancement of reactivity and selectivity of sodium borohydride for applications in organic synthesis Pages 137-151 Mariappan Periasamy, Muniappan Thirumalaikumar

Sterically encumbered terphenyl substituted primary pnictanes ArEH2 and their metallated derivatives ArE(H)Li (Ar=---C6H3-2,6-Trip2; Trip=2,4,6-triisopropylphenyl; E=N, P, As, Sb) Pages 152-160 Brendan Twamley, Cheong-Soo Hwang, Ned J. Hardman, Philip P. Power

Synthesis and properties of the 16-electron complex [(C5Me5)RuCl(PMeiPr2)] and of half-sandwich ruthenium hydrido complexes containing bulky monodentate phosphine ligands Pages 161-168 Manuel Jiménez Tenorio, M. Carmen Puerta, Pedro Valerga

Reaction of [Os3H2(CO)10] with the diyne Me3SiC2C2SiMe3 and the reactivity of the products towards [Co2(CO)8]: the X-ray structures of [Os3(μ-H)(CO)10{μ-η1-η2-HC2(SiMe3)C2(SiMe3)}], [Os3(μ-CO)(CO)9{μ3-η2-Me3SiC2C2SiMe3}] and [Os3(μ-H)(CO)9{μ3-η1:η2-;μ-η2-Me3SiC2C2[Co2(CO)6]}] Pages 169-176 Lionel P. Clarke, John E. Davies, Paul R. Raithby, Moira-Ann Rennie, Gregory P. Shields, Emma Sparr

Silatranyl, hydride complexes of osmium(II) and osmium(IV): crystal structure of Os(Si{OCH2CH2}3N)H3(PPh3)3 Pages 177-183 Clifton E. F. Rickard, Warren R. Roper, Scott D. Woodgate, L. James Wright

Synthesis, structure, ESI mass spectrum and magnetic property of a monocationic cluster complex of chromium-sulfide with a hydrido ligand [Cr6S8(H)(PEt3)6](BF4) Pages 184-188 Satoshi Kamiguchi, Taro Saito, Zentaro Honda

Si(CH2CH2SnH3)4 — a unique organotin hydride featuring 12 SnH units in a dendritic molecule. Single-crystal X-ray structures of tetrakis(2-stannylethylene)silane and tetrakis[2-(triphenylstannyl)ethylene]silane Pages 189-195 Herbert Schumann, Birgit C. Wassermann, Michaela Frackowiak, Bamidele Omotowa, Stefan Schutte, Janna Velder, Stefan H. Mühle, Werner Krause

The cluster dication [H6Ru4(C6H6)4]2+ revisited: the first cluster complex containing an intact dihydrogen ligand? Pages 196-203 Georg Süss-Fink*, Laurent Plasseraud, Aline Maisse-François, Helen Stoeckli-Evans, Heinz Berke*, Thomas Fox, Régis Gautier, Jean-Yves Saillard*

Index Page 204 Unknown

Index Pages 205-208 Unknown